Co-Catalyzed Radical Cycloaddition of [60]Fullerene with Active Dibromides: Selective Synthesis of Carbocycle-Fused Fullerene Monoadducts

被引：55

作者：

Lu, Shirong ^{[1
]}

Si, Weili ^{[1
]}

Bao, Ming ^{[2
]}

Yamamoto, Yoshinori ^{[1
,2
]}

Jin, Tienan ^{[1
]}

机构：

[1] Tohoku Univ, WPI Adv Inst Mat Res WPI AIMR, Sendai, Miyagi 9808577, Japan

[2] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 15期

关键词：

CHEMISTRY; HYDROFULLERENES; DIMERIZATION; C-60; SULFONAMIDES; DERIVATIVES; CYCLIZATION; ACCEPTOR; WATER;

D O I：

10.1021/ol401876n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.

引用

页码：4030 / 4033

页数：4

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