Anti-ablation performance of La2O3-modified ZrB2 coating on SiC-coated carbon/carbon composites

被引:16
作者
Chen, Miaomiao [1 ,2 ]
Yao, Xiyuan [1 ]
Feng, Guanghui [1 ]
Guo, Yao [1 ]
机构
[1] Northwestern Polytech Univ, Xian 710072, Peoples R China
[2] AVIC Chengdu Aircraft Ind Grp CO Ltd, Chengdu 610091, Peoples R China
关键词
C/C composites; Anti-ablation performance; ZrB2; coating; La2O3; RESISTANCE; OXIDATION; BEHAVIOR; LA2O3; MICROSTRUCTURE; PROTECTION; MECHANISM; PROPERTY; DESIGN; LAB6;
D O I
10.1016/j.ceramint.2020.08.038
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
La2O3-modified ZrB2 coating was prepared on SiC-coated C/C composites by supersonic atmospheric plasma spraying (SAPS) with the aim of improving the anti-ablation performance of C/C composites. The effect of La2O3 contents on the anti-ablation performance were investigated. The results indicated that the 10 vol % La2O3-ZrB2 coating shows excellent anti-ablation performance. After ablation for 120 s under low heat flux oxyacetylene flame (2400 kW/m(2)), the linear ablation rate and mass ablation are only - 0.0167 mu m/s and - 0.558 mg/s, respectively. After ablation for 30 s under high heat flux of oxyacetylene flame (4200 kW/m(2)), the coating still remains intact. The addition of 10 vol % La2O3 is capable of enhancing the anti-ablation performance of the ZrB2 coating. The La2O3 and La2Zr2O7 phases will be soften and melting during ablation, which can form a barrier to cover the surface and effectively prevent the erosion of oxyacetylene gas. Meanwhile, the generated ZrO2 particles play the role of pinning the molten layer, thus weakening the coating exfoliation by airflow erosion.
引用
收藏
页码:28758 / 28766
页数:9
相关论文
共 50 条
  • [21] Fabrication and ablation property of carbon/carbon composites with novel SiC-ZrB2 coating
    Huang, Dong
    Zhang, Ming-yu
    Huang, Qi-zhong
    Wang, Li-ping
    Tang, Xian
    Yang, Xin
    Tong, Kai
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2015, 25 (11) : 3708 - 3715
  • [22] Enhanced anti-ablation performance of carbon/carbon composites modified with ZrC-SiC
    Zhao, Zhigang
    Li, Kezhi
    Liu, Qing
    Li, Wei
    Zhang, Yulei
    VACUUM, 2018, 156 : 123 - 127
  • [23] Effect of ablative angles on the ablation behaviors of ZrB2-SiC modified carbon/carbon composites
    Wang, Chuang
    Li, Ke-zhi
    Lu, Ying
    Peng, Lei
    Li, Bingliang
    Zhao, Zhigang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 745 : 569 - 578
  • [24] The ablation behaviors of ZrB2-based UHTC coating with La2O3-modified SiC bond coat
    Li, Jiayan
    Li, Gui
    Wang, Yulong
    Wang, Bo
    Li, Yuanqi
    Hao, Jianjie
    CERAMICS INTERNATIONAL, 2024, 50 (06) : 9139 - 9148
  • [25] Ablation resistance of TaC-modified HfC coating prepared by supersonic plasma spraying for SiC-coated carbon/carbon composites
    Feng, Guanghui
    Li, Hejun
    Yao, Xiyuan
    Chen, Miaomiao
    Xue, Yibei
    CERAMICS INTERNATIONAL, 2019, 45 (14) : 17936 - 17945
  • [26] Ablation behavior of ZrB2-SiC protective coating for carbon/carbon composites
    Wang, Dini
    Zeng, Yi
    Xiong, Xiang
    Li, Guodong
    Chen, Zhaoke
    Sun, Wei
    Wang, Yalei
    CERAMICS INTERNATIONAL, 2015, 41 (06) : 7677 - 7686
  • [27] A multilayer MoSi2-SiC-B coating to protect SiC-coated carbon/carbon composites against oxidation
    Fu, Qiangang
    Zou, Xu
    Chu, Yanhui
    Li, Hejun
    Zou, Jizhao
    Gu, Caige
    VACUUM, 2012, 86 (12) : 1960 - 1963
  • [28] Preparation of oxidation protective ZrB2-SiC coating by in-situ reaction method on SiC-coated carbon/carbon composites
    Ren, Xuanru
    Li, Hejun
    Chu, Yanhui
    Fu, Qiangang
    Li, Kezhi
    SURFACE & COATINGS TECHNOLOGY, 2014, 247 : 61 - 67
  • [29] ZrB2-SiC ceramics coating for Cf/SiC composites: Microstructure and anti-ablation mechanism
    Xiang, Yang
    Peng, Zhi-hang
    Wang, Yi
    Xing, Zhong-fang
    Cao, Feng
    JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 750 : 857 - 862
  • [30] An optimized strategy toward multilayer ablation coating for SiC-coated carbon/carbon composites based on experiment and simulation
    Feng, Guanghui
    Li, Hejun
    Yao, Xiyuan
    Sun, Jia
    Jia, Yujun
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2022, 42 (09) : 3802 - 3811