An effective n-type doping of ZnO thin films electrochemically synthetized was achieved by varying the chloride ion concentration in the starting electrolyte. The ratio between chloride and zinc cations was varied between 0 and 2 while the zinc concentration in the solution was kept constant. When the concentration of chloride in the bath increases an effective n-type doping of ZnO films takes place. n-type doping is evidenced by the rise of donors concentration, obtained from Mott-Schottky measurements, as well as from the blueshift observed in the optical gap owing to the Burstein-Moss effect. (C) 2013 The Electrochemical Society. All rights reserved.
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Sheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, EnglandSheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, England
Echendu, O. K.
Weerasinghe, A. R.
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Sheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, EnglandSheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, England
Weerasinghe, A. R.
Diso, D. G.
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Sheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, EnglandSheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, England
Diso, D. G.
Fauzi, F.
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Sheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, EnglandSheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, England
Fauzi, F.
Dharmadasa, I. M.
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Sheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, EnglandSheffield Hallam Univ, Elect Mat & Sensors Grp, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, England