An effective n-type doping of ZnO thin films electrochemically synthetized was achieved by varying the chloride ion concentration in the starting electrolyte. The ratio between chloride and zinc cations was varied between 0 and 2 while the zinc concentration in the solution was kept constant. When the concentration of chloride in the bath increases an effective n-type doping of ZnO films takes place. n-type doping is evidenced by the rise of donors concentration, obtained from Mott-Schottky measurements, as well as from the blueshift observed in the optical gap owing to the Burstein-Moss effect. (C) 2013 The Electrochemical Society. All rights reserved.
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Shantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R China
City Univ Hong Kong, Dept Phys, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R ChinaShantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R China
Liu, Chao Ping
Ho, Chun Yuen
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City Univ Hong Kong, Dept Phys, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R ChinaShantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R China
Ho, Chun Yuen
Egbo, Kingsley O.
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City Univ Hong Kong, Dept Phys, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R ChinaShantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R China
Egbo, Kingsley O.
Li, Zhan Hua
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Shantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R ChinaShantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R China
Li, Zhan Hua
Xu, Cong Kang
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Shantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R ChinaShantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R China
Xu, Cong Kang
Yu, Kin Man
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City Univ Hong Kong, Dept Phys, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R ChinaShantou Univ, Coll Sci, Res Ctr Adv Opt & Photoelect, Dept Phys, Shantou 515063, Guangdong, Peoples R China