Catalytic Deoxydehydration of Glycols with Alcohol Reductants

被引：75

作者：

Boucher-Jacobs, Camille ^{[1
]}

Nicholas, Kenneth M. ^{[1
]}

机构：

[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA

来源：

CHEMSUSCHEM | 2013年 / 6卷 / 04期

关键词：

alkenes; deoxydehydration; heterogeneous catalysis; hydrogen transfer; rhenium; ALDEHYDE-BISULFITE ADDUCTS; BIOMASS; DEOXYGENATION; CONVERSION; DIOLS; CYCLOREVERSION; REGENERATION; FEEDSTOCKS; CHEMICALS; PRODUCTS;

D O I：

10.1002/cssc.201200781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Top shelf dehydration: Ammonium perrhenate catalysts combined with benzylic alcohol reductants are used for the efficient deoxydehydration of glycols to olefins. The olefin and aldehyde products can be easily separated and isolated. It is also demonstrated that the catalyst can be recovered and reused because of its low solubility in aromatic solvents. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：597 / 599

页数：3

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