The effect of ion milling on electrical properties of vacancy- and arsenic-doped p-Hg(1-x)Cd(x)Te (MCT) (x similar to 0.22) has been studied. Samples for the study were fabricated by thermal annealing of n-type heterostructures grown by molecular beam epitaxy ( MBE) on GaAs. Their behaviour under ion milling was compared to that of MCT bulk samples and films grown by liquid and vapour phase epitaxy. Residual donor concentration in the MBE-grown structures was found to be of the order of 10(15) cm(-3), which is typical for MCT. Unique to the MBE structures was high electron concentration (similar to 10(17) cm(-3)) straight after the milling. We suppose that this fact reflected ion-milling-induced activation of an initially neutral defect, which was formed in the heterostructures during the growth. A possible nature of the defect is discussed.