Thiol elimination from tris[2-(phenylthio)ethyl]phosphine oxide: a convenient route to trivinylphosphine oxide

被引：7
作者：
Gusarova, NK [1 ]
Chernysheva, NA [1 ]
Arbuzova, SN [1 ]
Bogdanova, MV [1 ]
Ivanova, NI [1 ]
Kudryavtsev, AA [1 ]
Trofimov, BA [1 ]
机构：
[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
来源：
MENDELEEV COMMUNICATIONS | 2006年 / 16卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1070/MC2006v016n01ABEH002248
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Tris[2-(phenylthio)ethyl]phosphine oxide reacts with sodium amide to afford trivinylphosphine oxide in a good yield. The reaction involves the generation of phosphoryl-stabilised carbanions, which further eliminate benzene thiolate anions.
引用
收藏
页码：31 / 31
页数：1
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