Nickel(II) complexes supported by a fluorinated β-diketiminate backbone ligand:: synthesis, catalytic activity toward norbornene polymerization, and the oxygenated species

被引：36

作者：

Li, YF ^{[1
]}

Jiang, L ^{[1
]}

Wang, LY ^{[1
]}

Gao, HY ^{[1
]}

Zhu, FM ^{[1
]}

Wu, Q ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Inst Polymer Sci, Guangzhou 510275, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2006年 / 20卷 / 03期

关键词：

beta-diketiminate; nickel; norbornene; vinyl polymerization; hydroxylation;

D O I：

10.1002/aoc.1042

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The reaction of the lithium salt of backbone fluorinated beta-diketiminate ligands, ArNC(CF3)CHC(CF3) NArLi, with trans-[NiCl(Ph)(PPh3)(2)] gives nickel (II) complexes, ArNC(CF3)CHC(CF3)NAr(Ph) (PPh3)Ni (Ar = 2,6-Me2C6H3: 1; 2,6-(Pr2C6H3)-Pr-i:2). When activated by methylaluminoxane (MAO), both complexes polymerize norbornene rapidly via a vinyl-type polymerization mechanism. Treatment of nickel complex I with oxygen gives rise to intramolecular aerobic hydroxylation. The oxygenated species 3 was characterized by X-ray crystallography. Copyright (c) 2006 John Wiley & Sons, Ltd.

引用

页码：181 / 186

页数：6

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