Chemistry on Boranils: An Entry to Functionalized Fluorescent Dyes

被引：88

作者：

Frath, Denis ^{[1
]}

Azizi, Sebastien ^{[1
]}

Ulrich, Gilles ^{[1
]}

Ziessel, Raymond ^{[1
]}

机构：

[1] CNRS, Ecole Chim Polymeres Mat Strasbourg ECPM, UMR 7515, Lab Chim Organ & Spect Avancees LCOSA, F-67087 Strasbourg 02, France

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 18期

关键词：

ISOTHIOCYANATE;

D O I：

10.1021/ol3020573

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Boranil fluorophore bearing a nitro-phenyl group has been selectively reduced to its anilino form and then successfully converted to amide, imine, urea, and thiourea derivatives which are fluorescent dyes. Its isolated isothiocyanate intermediate derivative was used in a model labeling experiment with Bovine Serum Albumin (BSA). The purified labeled-BSA exhibits strong luminescence (Phi(f) = 47%) in a phosphate buffer at pH = 7.4.

引用

页码：4774 / 4777

页数：4

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