Assessment of hydrogen storage by physisorption in porous materials

被引：84

作者：

Bastos-Neto, Moises ^{[1
]}

Patzschke, Christin ^{[1
]}

Lange, Marcus ^{[1
]}

Moellmer, Jens ^{[1
]}

Moeller, Andreas ^{[1
]}

Fichtner, Sven ^{[2
]}

Schrage, Christian ^{[2
]}

Laessig, Daniel ^{[3
]}

Lincke, Joerg ^{[3
]}

Staudt, Reiner ^{[4
]}

Krautscheid, Harald ^{[3
]}

Glaeser, Roger ^{[1
,3
]}

机构：

[1] Univ Leipzig, Inst Nichtklass Chem eV, D-04318 Leipzig, Germany

[2] Adsor Tech GmbH, D-14727 Premnitz, Germany

[3] Univ Leipzig, Fak Chem & Mineral, D-04103 Leipzig, Germany

[4] Hsch Offenburg, Fak Maschinenbau & Verfahrenstech M V, D-77652 Offenburg, Germany

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2012年 / 5卷 / 08期

关键词：

METAL-ORGANIC FRAMEWORKS; HIGH-PRESSURE ADSORPTION; GIBBSIAN SURFACE EXCESS; CARBON NANOTUBES; ACTIVATED CARBONS; SILICA AEROGELS; GAS-ADSORPTION; CO2; ADSORPTION; ZEOLITE-X; METHANE;

D O I：

10.1039/c2ee22037g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As a basis for the evaluation of hydrogen storage by physisorption, adsorption isotherms of H-2 were experimentally determined for several porous materials at 77 K and 298 K at pressures up to 15 MPa. Activated carbons and MOFs were studied as the most promising materials for this purpose. A noble focus was given on how to determine whether a material is feasible for hydrogen storage or not, dealing with an assessment method and the pitfalls and problems of determining the viability. For a quantitative evaluation of the feasibility of sorptive hydrogen storage in a general analysis, it is suggested to compare the stored amount in a theoretical tank filled with adsorbents to the amount of hydrogen stored in the same tank without adsorbents. According to our results, an "ideal" sorbent for hydrogen storage at 77 K is calculated to exhibit a specific surface area of >2580 m(2) g(-1) and a micropore volume of >1.58 cm(3) g(-1).

引用

页码：8294 / 8303

页数：10

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