Application of products of reaction between melamine and glycidol as substrates for oligoetherols and polyurethane foams containing 1,3,5-triazine rings

被引：12

作者：

Cyzio, Karina ^{[1
]}

Lubczak, Jacek ^{[1
]}

机构：

[1] Rzeszow Univ Technol, Dept Organ Chem, PL-35959 Rzeszow, Poland

来源：

POLYMER INTERNATIONAL | 2013年 / 62卷 / 12期

关键词：

melamine; glycidol; alkylene carbonates; oxiranes; oligoetherols; polyurethane foams; ALKYLENE CARBONATES; POLYETHEROLS; COMPOSITE; PHOSPHATE;

D O I：

10.1002/pi.4476

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hydroxyalkyl derivatives of melamine were obtained by addition of melamine to glycidol. These derivatives were then used to obtain multifunctional oligoetherols by reaction with oxiranes and alkylene carbonates. The structure and properties of the oligoetherols were studied in detail. The oligoetherols were then used to obtain polyurethane foams of enhanced thermal stability. The foams showed marked thermal resistance at 200 degrees C. The beneficial feature of the obtained foams was their increased compression strength after thermal exposure. (c) 2013 Society of Chemical Industry

引用

页码：1735 / 1743

页数：9

共 30 条

[1]

[Anonymous], 35822002 PNEN ISO

[2]

Brojer Z., 1972, Epoxy Resins

[3]

[Cellular Plastics Polish Committee for Standardization], 8441978 PNEN ISO

[4] Thermal and flame retardation properties of melamine phosphate-modified epoxy resins [J].

Chen, WY ;

Wang, YZ ;

Chang, FC .

JOURNAL OF POLYMER RESEARCH, 2004, 11 (02) :109-117

[5] Preparation of flame retardant polyamide 6 composite with melamine cyanurate nanoparticles in situ formed in extrusion process [J].

Chen, Yinghong ;

Wang, Qi ;

Yan, Wei ;

Tang, Hongmei .

POLYMER DEGRADATION AND STABILITY, 2006, 91 (11) :2632-2643

[6] Thermal degradation of urethane modified polyisocyanurate foams based on aliphatic and aromatic polyester polyol [J].

Dominguez-Rosado, E ;

Liggat, JJ ;

Snape, CE ;

Eling, B ;

Pichtel, J .

POLYMER DEGRADATION AND STABILITY, 2002, 78 (01) :1-5

[7]

Erics W, 1941, US Patent, Patent No. 2381121

[8]

Erics W, 1943, US Patent, Patent No. 2414289

[9]

Glinka Z, 1966, POLIMERY WARSAW, V11, P167

[10]

Goodman S.H., 1999, Handbook of Thermoset Plastics, V2

← 1 2 3 →