Synthesis and Properties of Novel Calix[4]Resorcinols Containing Phosphonium Substituents

被引:5
作者
Kibardina, Liudmila K. [1 ]
Knyazeva, Irina R. [1 ]
Sokolova, Victoria I. [1 ]
Vagapova, Guzalia I. [1 ]
Zakharova, Lucia Ya. [1 ]
Burilov, Alexander R. [1 ]
Pudovik, Michael A. [1 ]
机构
[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
基金
俄罗斯基础研究基金会;
关键词
Acetal; phosphonic salt; resorcinol; polyphenol; condensation; calix[4]resorcinol; critical micelle concentration; aggregation; LOWER RIM; FRAGMENTS; MOLECULE;
D O I
10.1080/10426507.2012.729873
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Condensation of resorcinol and its derivatives with novel phosphonium-substituted acetals under conditions of acidic catalysis yields either calix[4]resorcinols containing four phosphonium fragments or phosphonium salts including diarylmethane moiety depending on the structure of the phosphorus-containing reagent. The latter, in turn, undergo condensation with propionic aldehyde forming new calix[4]resorcinols with alternating phosphonium and ethyl substituents, which have remarkable surface-active properties.
引用
收藏
页码:1 / 3
页数:3
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