Dynamic structural conversion in a spin-crossover cobalt(II) compound with long alkyl chains

被引：74

作者：

Hayami, Shinya ^{[1
]}

Murata, Kazuhisa ^{[1
]}

Urakami, Daisuke ^{[1
]}

Kojima, Yoshihiro ^{[1
]}

Akita, Motoko ^{[1
]}

Inoue, Katsuya ^{[1
,2
]}

机构：

[1] Hiroshima Univ, Grad Sch Sci, Dept Chem, Higashihiroshima 7398526, Japan

[2] Hiroshima Univ, Inst Adv Mat Res, Higashihiroshima 7398526, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 48期

关键词：

D O I：

10.1039/b814415j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cobalt(II) compound [Co(C14-terpy)(2)](BF4)(2)center dot MeOH (1) with long alkyl chains was prepared, and exhibited unique SCO at T(1) = 50 K and spin transition at T(2)up arrow = 206 K and T(2)down arrow = 184 K with hysteresis (Delta T = 22 K) accompanying the motion of the long alkyl chains.

引用

页码：6510 / 6512

页数：3

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