Tunable Multicolor Emission and Energy Transfer of Sb3+/Mn2+ Codoped Phosphate Glasses by Design

被引：22

作者：

Zeng, Huidan ^{[1
]}

Yu, Qing ^{[1
]}

Wang, Zhaofeng ^{[2
,3
]}

Sun, Luyi ^{[2
,3
]}

Ren, Jing ^{[1
]}

Chen, Guorong ^{[1
]}

Qiu, Jianrong ^{[4
]}

机构：

[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China

[2] Texas State Univ San Marcos, Dept Chem & Biochem, San Marcos, TX 78666 USA

[3] Texas State Univ San Marcos, Mat Sci Engn & Commercializat Program, San Marcos, TX 78666 USA

[4] S China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Peoples R China

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2013年 / 96卷 / 08期

基金：

上海市自然科学基金; 美国国家科学基金会;

关键词：

HYDROTHERMAL SYNTHESIS; LUMINESCENT PROPERTIES; OPTICAL-PROPERTIES; ION; FLUORESCENCE; NANOCRYSTALS; SB3+;

D O I：

10.1111/jace.12481

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In this work, the luminescent properties of Sb3+/Mn2+ codoped 60P(2)O(5)-40MgO glass are presented. White light photoluminescence combining blue and orange-red light was observed under ultraviolet light excitation. The emission spectra showed that the blue emission intensity of Sb3+ decreased significantly whereas the red emission intensity of Mn2+ increased with the increasing concentration of Mn2+ ions. Meanwhile, by maintaining the concentration of MnO (2.0mol%) and increasing concentration of Sb2O3, both the blue emission and red emission were enhanced remarkably. The energy transfer from Sb3+ to Mn2+ ions via the dipole-quadrupole interaction was confirmed.

引用

页码：2476 / 2480

页数：5

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