Dynamic rheological behavior and mechanical properties of PVC/CPE/MAP-POSS nanocomposites

被引:15
作者
Du, Yonggang [1 ,2 ]
Gao, Jungang [1 ]
Yang, Jianbo [1 ]
Liu, Xiaoqian [1 ]
机构
[1] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
[2] Hengshui Univ, Dept Chem & Engn, Hengshui 053000, Peoples R China
关键词
rheology; poly(vinyl chloride); nanostructured polymers; blends; mechanical properties; CHLORIDE) PVC COMPOUNDS; CHLORINATED POLYETHYLENE; POLY(VINYL; BLENDS;
D O I
10.1002/app.38719
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(vinyl chloride)/chlorinated polyethylene (PVC/CPE)/methylacryloylpropyl-containing polyhedral oligomeric silsesquioxane (MAPPOSS) nanocomposites are prepared. The plastic behavior and dynamic rheological behavior of PVC/CPE/MAPPOSS are investigated. The influences of composition on dynamic storage modulus G, loss modulus G, and complex viscosity * of PVC/CPE/MAPPOSS melts are discussed. The dynamic mechanical properties, mechanical properties, and morphology are determined. The results show that both plastic time and balance torque of the nanocomposites decrease, but the G, G, and * all increase with increasing MAPPOSS content. The maximum value of the dynamic mechanical loss tan decreases and elasticity increases when MAPPOSS is added. The impact strength of the nanocomposites increases with increasing MAPPOSS content and has the best value at 10% content of MAPPOSS, which is 5.38 kJ/m2 higher than that of the blend without MAPPOSS. The MAPPOSS can be used as an efficient process aid and impact aid for the PVC/CPE blend. (c) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
引用
收藏
页码:174 / 180
页数:7
相关论文
共 28 条
[11]   Rheology of poly(ethylene oxide)/organoclay nanocomposites [J].
Hyun, YH ;
Lim, ST ;
Choi, HJ ;
Jhon, MS .
MACROMOLECULES, 2001, 34 (23) :8084-8093
[12]   Preparation and linear rheological behavior of polypropylene/MMT nanocomposites [J].
Jian, L ;
Zhou, CX ;
Gang, W ;
Wei, Y ;
Ying, T ;
Qing, L .
POLYMER COMPOSITES, 2003, 24 (03) :323-331
[13]  
Larson R. G., 1999, STRUCTURE RHEOLOGY C, P82
[14]   The Roles of Polyacrylate in Poly(vinyl chloride)-Lignin Composites [J].
Liu, Feiyue ;
Xu, Kai ;
Chen, Mingcai ;
Cao, Derong .
POLYMER COMPOSITES, 2011, 32 (09) :1399-1407
[15]   Polyacrylamide-clay nanocomposite hydrogels: Rheological and light scattering characterization [J].
Okay, Oguz ;
Oppermann, Wilhelm .
MACROMOLECULES, 2007, 40 (09) :3378-3387
[16]   Preparation, characterization, and properties of poly(vinyl chloride)/organophilic-montmorillonite nanocomposites [J].
Ren, TB ;
Yang, J ;
Huang, YX ;
Ren, J ;
Liu, Y .
POLYMER COMPOSITES, 2006, 27 (01) :55-64
[17]  
Saito H, 2002, Japan Patent, Patent No. [31:285387, 31285387]
[18]   Effects of acrylic-based processing aids on processibility, rheology, thermal and structural stability, and mechanical properties of PVC/wood-sawdust composites [J].
Sombatsompop, N ;
Phromchirasuk, C .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 92 (02) :782-790
[19]   Polyhedral oligomeric silsesquioxane as a novel plasticizer for poly(vinyl chloride) [J].
Soong, Sharon Y. ;
Cohen, Robert E. ;
Boyce, Mary C. .
POLYMER, 2007, 48 (05) :1410-1418
[20]   Rate-dependent deformation behavior of POSS-filled and plasticized poly(vinyl chloride) [J].
Soong, SY ;
Cohen, RE ;
Boyce, MC ;
Mulliken, AD .
MACROMOLECULES, 2006, 39 (08) :2900-2908