Kinetic model of semibatch polymerization with ABg monomer and Bf core

被引：0

作者：

Zhou, Zhiping ^{[1
]}

Wu, Minjie ^{[1
]}

机构：

[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China

来源：

ADVANCES IN CHEMISTRY RESEARCH II, PTS 1-3 | 2012年 / 554-556卷

关键词：

Hyperbranched polymer; Kinetics; Molecular weight distribution; Polydispersity; MOLECULAR-WEIGHT DISTRIBUTION; CONDENSING VINYL POLYMERIZATION; HYPERBRANCHED POLYMERS; MULTIFUNCTIONAL CORE; POLYCONDENSATION; SIMULATION; INITIATOR;

D O I：

10.4028/www.scientific.net/AMR.554-556.172

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetics of semibatch polymerization (i.e. slow monomer addition) with AB(g) monomer and B-f core was developed. The analytical expressions of molecular parameters, such as the molecular size distribution function, the average degree of polymerization and polydispersity index, were derived, which dependent on the structure of monomer and core molecule used. The molecular parameters are adjustable by selecting suitable core functionality (f), monomer functionality (g) and core/monomer ratio (alpha). Comparison with the batch (one-pot) polymerization indicates that the semibatch polymerization can extremely narrow the molecular weight distribution for the products made of AB(g) monomer and B-f core.

引用

页码：172 / 176

页数：5

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