The self-assembly and magnetic properties of a Ni(II)8(μ4-hydroxo)6 cube with μ2-pyrazolate as an exogeneous ancillary ligand

被引：31
|
作者：
Xu, Jing-Yuan [2 ]
Qiao, Xin [2 ]
Song, Hai-Bin [1 ]
Yan, Shi-Ping [1 ]
Liao, Dai-Zheng [1 ]
Gao, Song [3 ]
Journaux, Yves [4 ]
Cano, Joan [5 ,6 ,7 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Tianjin Med Univ, Coll Pharm, Tianjin 300070, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
[4] Univ Paris 06, CNRS, Lab Chim Inorgan & Mat Mol, UPMC,UMR 7071, Paris, France
[5] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[6] Univ Barcelona, IQTC, Barcelona, Spain
[7] ICREA, Barcelona, Spain
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 47期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1039/b813705f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel octanuclear hydroxonickel(II) complex possessing a unprecedented cube molecular structure with eight Ni(II) ions at each vertex, six mu(4)-OH- groups closing each face and twelve exo-bidentate pyrazolate ligands (mu(2)-pz) spanning each edge, has been synthesized and its magnetic properties investigated.
引用
收藏
页码：6414 / 6416
页数：3
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