Synthesis and Supramolecular Structure of Bis-zinc(II) Tetraformate Tetrahydrate Polymer[Zn2(HCOO-)4(H2O)4]n

被引:5
|
作者
Wang, Li [1 ]
Dong, Xiu-Yan [1 ]
Zhao, Li [1 ]
Yang, Yu-Hua [1 ]
机构
[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China
关键词
Monooxime compound; Synthesis; Crystal structure; Supramolecular interaction; CRYSTAL-STRUCTURE; BISOXIME LIGANDS; COMPLEXES; ZINC(II); CLUSTER;
D O I
10.14233/ajchem.2013.13980
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The polymeric compound bis-zinc(II) tetraformate tetrahydrate with the m.f. [Zn-2(HCOO-)(4)(H2O)(4)](n), was synthesized respectively, by the reaction of zinc(II), acetate dihydrate with 2',2'-[1,1'-(propane-1,3-diyldioxy)bis(nitrilomethylidyne)di-1-naphthol (H2L) in ethanol. The molecule-crystallizes the monoclinic system, adopts a polymer conformation. The crystal structure indicates that it is an infinite three-dimension supramolecular network complex.
引用
收藏
页码:4055 / 4057
页数:3
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