Stereocontrolled approach to the highly functionalized bicyclo[3.2.0] heptane core of bielschowskysin through intramolecular Cu(I)-catalyzed [2+2] photocycloaddition

被引：22

作者：

Jana, Anupam ^{[1
]}

Mondal, Sujit ^{[1
]}

Hossain, Md Firoj ^{[1
]}

Ghosh, Subrata ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, W Bengal, India

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 50期

关键词：

Cycloaddition; Photochemistry; Stereocontrol; Terpenes; DERIVATIVES; CATALYSIS;

D O I：

10.1016/j.tetlet.2012.10.018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A direct route for the synthesis of highly functionalized bicyclo[3.2.0]heptane core containing the bridged lactone with the functionalized C-12 substituent of bielschowslcysin is reported. The key step involves a stereoselective Cu (I)-catalyzed [2+2] photocycloaddition of a 1,6-diene embedded in a sugar derivative. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：6830 / 6833

页数：4

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