Catalytic activity of unsupported gold nanoparticles

被引：192

作者：

Mikami, Yusuke ^{[1
]}

Dhakshinamoorthy, Amarajothi ^{[1
]}

Alvaro, Mercedes ^{[1
]}

Garcia, Hermenegildo ^{[1
]}

机构：

[1] Univ Politecn Valencia, Inst Univ Tecnol Quim CSIC UPV, Dept Quim, Valencia 46022, Spain

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 01期

关键词：

LIQUID-PHASE OXIDATION; AEROBIC OXIDATION; CO OXIDATION; PARTICLE-SIZE; CHEMOSELECTIVE HYDROGENATION; SELECTIVE OXIDATION; CRYSTAL-STRUCTURE; ROOM-TEMPERATURE; FACILE SYNTHESIS; COLLOIDAL GOLD;

D O I：

10.1039/c2cy20068f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article reviews some of the compelling evidence showing that colloidal gold nanoparticles without any solid support exhibit intrinsic catalytic activity for some of the typical gold-catalyzed reactions including CO oxidation, aerobic oxidation of alcohols and diols, borohydride reductions and carbon-carbon cross coupling reaction among other reactions. A critical view of the state-of-the-art indicating open issues such as the role of the nature and concentration of the ligand and the possibility of preparing colloidal samples with preferential crystallographic planes is provided.

引用

页码：58 / 69

页数：12

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