Optimization of nickel removal using liquid-liquid extraction and response surface methodology

被引:25
作者
Talebi, Amir [1 ]
Teng, Tjoon Tow [1 ]
Alkarkhi, Abbas F. M. [1 ]
Norli, I. [1 ]
Low, Ling Wei [1 ]
机构
[1] Univ Sains Malaysia, Sch Ind Technol, George Town 11800, Malaysia
关键词
Response surface methodology; Liquid-liquid extraction; Di-(2-ethylhexyl) phosphoric acid (D2EHPA); Face-centered composite design; INDUSTRIAL WASTE-WATER; AQUEOUS-SOLUTION; SOLVENT-EXTRACTION; HEAVY-METALS; PHOSPHORIC-ACID; SODIUM-SALTS; MEMBRANE; RECOVERY; D2EHPA; ADSORPTION;
D O I
10.1080/19443994.2012.696432
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The nickel extraction efficiency by means of liquid-liquid extraction (LLE) method was studied using response surface methodology; six parameters were identified as influential factors on nickel removal efficiency as the response. However, on screening experiments, only two factors were selected: pH and di-(2-ethylhexyl) phosphoric acid (D2EHPA) concentration. Face-centered composite design (FCCD) was applied in order to determine the optimum conditions for nickel removal by LLE. The results of FCCD showed that a second-order model described the relationship between the factors and nickel removal properly. Results showed that the optimum conditions are pH 1.1 and D2EHPA concentration 0.2 M, where 95.57% of nickel removal was achieved.
引用
收藏
页码:334 / 340
页数:7
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