Three-component reaction between trivalent phosphorus nucleophiles, dialkyl acetylenedicarboxylates and (2,4-dinitrophenyl) acetic acid

被引：2

作者：

Hassanabadi, Alireza ^{[1
]}

Mosslemin, Mohammad H. ^{[2
]}

Abyar, Elaheh ^{[2
]}

Taleb-Malamiri, Mohammad ^{[2
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Zahedan Branch, Zahedan, Iran

[2] Islamic Azad Univ, Dept Chem, Yazd Branch, Yazd, Iran

来源：

JOURNAL OF CHEMICAL RESEARCH | 2012年 / 08期

关键词：

(2,4-dinitrophenyl)acetic acid; dialkyl acetylenedicarboxylate; phosphites; stereoselective synthesis; phosphorus ylides; triphenylphosphine; ONE-POT SYNTHESIS; DIMETHYL ACETYLENEDICARBOXYLATE; PHOSPHITES; DERIVATIVES;

D O I：

10.3184/174751912X13403013285904

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A three-component reaction between dialkyl acetylenedicarboxylates (DAADs) and phosphites in the presence of (2,4-dinitrophenyl) acetic acid leads to dialkyl 2-(dialkoxyphosphoryl)-3-[3-acetyl-2-(2,4-dinitrophenyl)-4-oxosuccinates in excellent yields. A similar reaction with triphenylphosphine, instead of phosphites, produces the stabilised phosphoranes in good yields.

引用

页码：497 / 499

页数：3

共 16 条

[1] Alizadeh A., 2009, SYNTHESIS-STUTTGART, V3, P464
[2] Anary-Abbasinejad M., 2007, J CHEM RES, P257
[3] Anary-Abbasinejad M, 2007, J CHEM RES, P574
[4] Anary-Abbasinejad M, 2007, J CHEM RES, P475
[5] Anary-Abbasinejad M, 2007, J CHEM RES, P455
[6] Stereoselective synthesis of 3-[2-(dialkoxyphosphoryl)-1,2-dialkoxy-carbonyl-ethyl]-4-hydroxycoumarins by reaction between trialkyl phosphites, dialkyl acetylenedicarboxylates and 4-hydroxycoumarin
Anary-Abbasinejad, Mohammad
Charkhati, Khadijeh
Hassanabadi, Alireza
[J]. JOURNAL OF CHEMICAL RESEARCH, 2009, (05) : 319 - 321
[7] Engel R., 1988, SYNTHESIS CARBON PHO
[8] SYNTHESIS OF DIALKYL 2-(DIALKOXYPHOSPHORYL)-3-(4-OXO-4,5-DIHYDRO-THIAZOLE-2-YL SULFANYL) SUCCINATES
Hassanabadi, Alireza
Mosslemin, Mohammad H.
Salari, Shabnam
Landi, Mahnoush Momeni
[J]. SYNTHETIC COMMUNICATIONS, 2012, 42 (15) : 2309 - 2317
[9] Three-component and one-pot reaction between aromatic oximes and dialkyl acetylenedicarboxylates in the presence of trimethyl phosphite
Hassanabadi, Alireza
Anary-Abbasinejad, Mohammad
Dehghan, Alimohammad
Taraghi, Fereshteh
Shams, Nasim
[J]. JOURNAL OF CHEMICAL RESEARCH, 2011, (06) : 368 - 370
[10] Johnson A.W., 1993, YLIDES IMINES PHOSPH, P386

← 1 2 →