Synthesis of α-ester-β-keto peroxides via iron-catalyzed carbonylation-peroxidation of α,β-unsaturated esters

被引：50

作者：

Liu, Kaisheng ^{[1
]}

Li, Yuanming ^{[1
]}

Zheng, Xiaojian ^{[1
]}

Liu, Weiping ^{[1
]}

Li, Zhiping ^{[1
,2
]}

机构：

[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

[2] China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China

来源：

TETRAHEDRON | 2012年 / 68卷 / 50期

基金：

美国国家科学基金会;

关键词：

Iron catalysis; Organic peroxides; Peroxidation; Carbonylation; Alkene di-functionalization; TERT-BUTYL HYDROPEROXIDE; RADICAL REACTIONS; MIXED PEROXIDES; CHEMISTRY; OXIDATION; ALKENES; ALDEHYDES;

D O I：

10.1016/j.tet.2012.09.110

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general and practical method for the synthesis of alpha-ester-beta-keto peroxides has been achieved by iron-catalyzed three-component reactions of alkenes, aldehydes, and TBHP. A wide variety of functionalized organic peroxides were synthesized efficiently and selectively. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：10333 / 10337

页数：5

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