Selective hydrogenation of 1,10-phenanthrolines by silica-supported palladium nanoparticles

被引：12

作者：

Bianchini, Claudio ^{[1
]}

Dal Santo, Vladimiro ^{[2
]}

Meli, Andrea ^{[1
]}

Moneti, Simonetta ^{[1
]}

Psaro, Rinaldo ^{[2
]}

Sordelli, Laura ^{[2
]}

Vizza, Francesco ^{[1
]}

机构：

[1] CNR, ICCOM, I-50019 Florence, Italy

[2] CNR, ISTM, I-20133 Milan, Italy

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 12-13期

关键词：

palladium catalysts; 1,10-phenanthroline; 2,9-dimethyl-1,10-phenanthroline; hydrogenation; heterogeneous catalysis;

D O I：

10.1016/j.ica.2008.03.099

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalytic hydrogenation of 1,10-phenanthroline (Phen) or 2,9-dimethyl-1,10- phenanthroline (DMPhen) has been achieved using silica-supported palladium nanoparticles (Pd/SiO2) with metal contents of 1.98 or 9.95 wt%. With either catalyst, the hydrogenation regiochemistry has been effectively controlled by the reaction temperature. The catalyst with the higher metal content was selective for the hydrogenation of one heterocyclic ring of either substrate at 80 degrees C and for both external rings at 130 degrees C for Phen and at 160 degrees C for DMPhen. The catalyst with the lower metal content was more active and exhibited comparable selectivity. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：3677 / 3680

页数：4

共 18 条

[1] Hydrogenation of arenes over silica-supported catalysts that combine a grafted rhodium complex and palladium nanoparticles:: Evidence for substrate activation on Rhsingle-site-Pdmetal moieties
Barbaro, Pierluigi
Bianchini, Claudio
Dal Santo, Vladimiro
Meli, Andrea
Moneti, Simonetta
Psaro, Rinaldo
Scaffidi, Adriana
Sordelli, Laura
Vizza, Francesco
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (21) : 7065 - 7076
[2] THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS
BARRETT, EP
JOYNER, LG
HALENDA, PP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) : 373 - 380
[3] Hydrogenation of arenes over catalysts that combine a metal phase and a grafted metal complex: Role of the single-site catalyst
Bianchini, C
Dal Santo, V
Meli, A
Moneti, S
Moreno, M
Oberhauser, W
Psaro, R
Sordelli, L
Vizza, F
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (23) : 2636 - 2639
[4] Bianchini C, 2001, EUR J INORG CHEM, P43
[5] BIANCHINI C., 2002, APPL HOMOGENEOUS CAT, V3, P1099
[6] Adsorption of gases in multimolecular layers
Brunauer, S
Emmett, PH
Teller, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 : 309 - 319
[7] BUDZELAAR PHM, 1995, GNMR V4 0
[8] On the quantitative recycling of Raney-Nickel catalysts on a labscale
Czaplik, Waldemar M.
Neudoerfl, Joerg-M.
Jacobi von Wangelin, Axel
[J]. GREEN CHEMISTRY, 2007, 9 (11) : 1163 - 1165
[9] HYDROGENATION OF 1,10-PHENANTHROLINE
ECKHARD, IF
FIELDEN, R
SUMMERS, LA
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1975, 28 (05) : 1149 - 1151
[10] GRUNES J, 2004, NANOTECHNOLOGY CATAL, V1, pCH1

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