Cu3Nb2O8: A Multiferroic with Chiral Coupling to the Crystal Structure

被引:80
作者
Johnson, R. D. [1 ,2 ]
Nair, Sunil [1 ]
Chapon, L. C. [2 ]
Bombardi, A. [3 ]
Vecchini, C. [3 ]
Prabhakaran, D. [1 ]
Boothroyd, A. T. [1 ]
Radaelli, P. G. [1 ]
机构
[1] Univ Oxford, Dept Phys, Clarendon Lab, Oxford OX1 3PU, England
[2] Rutherford Appleton Lab STFC, ISIS Facil, Didcot OX11 0QX, Oxon, England
[3] Diamond Light Source, Didcot OX11 0DE, Oxon, England
基金
英国工程与自然科学研究理事会;
关键词
FERROELECTRIC POLARIZATION;
D O I
10.1103/PhysRevLett.107.137205
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
By combining bulk properties, neutron diffraction, and nonresonant x-ray diffraction measurements, we demonstrate that the new multiferroic Cu3Nb2O8 becomes polar simultaneously with the appearance of generalized helicoidal magnetic ordering. The electrical polarization is oriented perpendicularly to the common plane of rotation of the spins-an observation that cannot be reconciled with the conventional theory developed for cycloidal multiferroics. Our results are consistent with coupling between a macroscopic structural rotation, which is allowed in the paramagnetic group, and magnetically induced structural chirality.
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页数:5
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共 18 条
[11]   Magnetic control of ferroelectric polarization [J].
Kimura, T ;
Goto, T ;
Shintani, H ;
Ishizaka, K ;
Arima, T ;
Tokura, Y .
NATURE, 2003, 426 (6962) :55-58
[12]   Magnetically driven ferroelectric order in Ni3V2O8 -: art. no. 087205 [J].
Lawes, G ;
Harris, AB ;
Kimura, T ;
Rogado, N ;
Cava, RJ ;
Aharony, A ;
Entin-Wohlman, O ;
Yildirim, T ;
Kenzelmann, M ;
Broholm, C ;
Ramirez, AP .
PHYSICAL REVIEW LETTERS, 2005, 95 (08)
[13]   Ferroelectricity in spiral magnets [J].
Mostovoy, M .
PHYSICAL REVIEW LETTERS, 2006, 96 (06)
[14]   RECENT ADVANCES IN MAGNETIC-STRUCTURE DETERMINATION BY NEUTRON POWDER DIFFRACTION [J].
RODRIGUEZCARVAJAL, J .
PHYSICA B, 1993, 192 (1-2) :55-69
[15]   Spin-driven ferroelectricity in triangular lattice antiferromagnets ACrO2 (A=Cu, Ag, Li, or Na) [J].
Seki, S. ;
Onose, Y. ;
Tokura, Y. .
PHYSICAL REVIEW LETTERS, 2008, 101 (06)
[16]   Ferroelectric polarization flop in a frustrated magnet MnWO4 induced by a magnetic field [J].
Taniguchi, K. ;
Abe, N. ;
Takenobu, T. ;
Iwasa, Y. ;
Arima, T. .
PHYSICAL REVIEW LETTERS, 2006, 97 (09)
[17]   Pseudo-proper ferroelectricity and magnetoelectric effects in TbMnO3 [J].
Toledano, Pierre .
PHYSICAL REVIEW B, 2009, 79 (09)
[18]   Magnetic reversal of the ferroelectric polarization in a multiferroic spinel oxide [J].
Yamasaki, Y. ;
Miyasaka, S. ;
Kaneko, Y. ;
He, J. -P. ;
Arima, T. ;
Tokura, Y. .
PHYSICAL REVIEW LETTERS, 2006, 96 (20)