Chiral azacrown ethers derived from D-glucose as catalysts for enantioselective Michael addition

被引：66

作者：

Bako, P

Kiss, T

Toke, L

机构：

[1] TECH UNIV BUDAPEST,HUNGARIAN ACAD SCI,DEPT ORGAN CHEM TECHNOL,H-1521 BUDAPEST,HUNGARY

[2] TECH UNIV BUDAPEST,HUNGARIAN ACAD SCI,ORGAN CHEM TECHNOL RES GRP,H-1521 BUDAPEST,HUNGARY

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(97)01686-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral monoaza-crown ethers incorporating glucose units have been synthesized and applied as phase transfer catalysts in the enantioselective Michael addition of 2-nitropropane to a chalcone to give the corresponding adduct in enantiomeric excess up to 90%. (C) 1997 Elsevier Science Ltd.

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页码：7259 / 7262

页数：4

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