Synthesis and characterization of metallic copper nanoparticles via thermal decomposition

被引:223
作者
Salavati-Niasari, Masoud [1 ,2 ]
Davar, Fatemeh [2 ]
Mir, Noshin [2 ]
机构
[1] Univ Kashan, Inst Nano Sci & Nano Technol, Kashan, Iran
[2] Univ Kashan, Fac Sci, Dept Chem, Kashan, Iran
关键词
Nanomaterials; Copper nanoparticles; Inorganic materials; Optical materials and properties;
D O I
10.1016/j.poly.2008.08.020
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Copper oxalate was used as a precursor to prepare metallic copper nanoparticles by thermal decomposition. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy and UV-Vis spectroscopy. XRD analysis revealed broad pattern for fcc crystal structure of copper metal. The particle size by use Of Debye-Scherrer's equation was calculated to be about 40 nm. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3514 / 3518
页数:5
相关论文
共 40 条
[11]   Synthesis of oleate capped Cu nanoparticles by thermal decomposition [J].
Kim, Young Hwan ;
Lee, Don Keun ;
Jo, Beong Gi ;
Jeong, Ji Hean ;
Kang, Young Soo .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 284 :364-368
[12]   Assembly and self-organization of silver nanocrystal superlattices: Ordered "soft spheres" [J].
Korgel, BA ;
Fullam, S ;
Connolly, S ;
Fitzmaurice, D .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (43) :8379-8388
[13]   Temperature-controlled self-assembled synthesis of CuO,Cu2O and Cu nanoparticles through a single-precursor route [J].
Liu, Xiaowang ;
Geng, Baoyou ;
Du, Qingbo ;
Ma, Jinzhu ;
Liu, Xianming .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 448 (1-2) :7-14
[14]   Synthesis of copper nanowires via a complex-surfactant-assisted hydrothermal reduction process [J].
Liu, ZP ;
Yang, Y ;
Liang, JB ;
Hu, ZK ;
Li, S ;
Peng, S ;
Qian, YT .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (46) :12658-12661
[15]   Oxidation behaviour of copper nanorods [J].
Liu, ZW ;
Bando, Y .
CHEMICAL PHYSICS LETTERS, 2003, 378 (1-2) :85-88
[16]   Immobilization of copper in organic-inorganic hybrid materials: a highly efficient and reusable catalyst for the Ullmann diaryl etherification [J].
Miao, Tao ;
Wang, Lei .
TETRAHEDRON LETTERS, 2007, 48 (01) :95-99
[17]  
Nasibulin AG, 2001, J NANOPART RES, V3, P385
[18]   Selective one-pot synthesis of copper nanorods under surfactantless condition [J].
Panigrahi, S ;
Kundu, S ;
Ghosh, SK ;
Nath, S ;
Praharaj, S ;
Basu, S ;
Pal, T .
POLYHEDRON, 2006, 25 (05) :1263-1269
[19]   Synthesis and size control of monodisperse copper nanoparticles by polyol method [J].
Park, Bong Kyun ;
Jeong, Sunho ;
Kim, Dongjo ;
Moon, Jooho ;
Lim, Soonkwon ;
Kim, Jang Sub .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 311 (02) :417-424
[20]   Monodisperse nanoparticles of Ni and NiO: Synthesis, characterization, self-assembled superlattices, and catalytic applications in the Suzuki coupling reaction [J].
Park, J ;
Kang, E ;
Son, SU ;
Park, HM ;
Lee, MK ;
Kim, J ;
Kim, KW ;
Noh, HJ ;
Park, JH ;
Bae, CJ ;
Park, JG ;
Hyeon, T .
ADVANCED MATERIALS, 2005, 17 (04) :429-+