Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system

被引：65

作者：

Agabekov, Vladislav ^{[1
]}

Seiche, Wolfgang ^{[1
]}

Breit, Bernhard ^{[1
]}

机构：

[1] Univ Freiburg, Inst Organ Chem, D-79104 Freiburg, Germany

来源：

CHEMICAL SCIENCE | 2013年 / 4卷 / 06期

关键词：

COMBINATORIAL HOMOGENEOUS CATALYSIS; REGIOSELECTIVE HYDROFORMYLATION; BIDENTATE LIGANDS; TRIPHENYL PHOSPHITE; TERMINAL ALKENES; METAL CATALYSIS; BASE-PAIR; COMPLEX; ORGANOCATALYSIS; CONSTRUCTION;

D O I：

10.1039/c3sc50725d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroformylation of alkynes is an underdeveloped atom-economic and redox-neutral method to prepare enals. Applying a new electron poor self-assembling ligand system provides the first general rhodium-catalyst for the chemo- and stereoselective hydroformylation of dialkyl- as well as diaryl-substituted alkynes to furnish enals in excellent chemo- and stereoselectivity.

引用

页码：2418 / 2422

页数：5

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