Ligand-free palladium-catalyzed decarboxylative coupling reactions of aryl iodides and alkynyl carboxylic acids

被引：18

作者：

Pyo, Ayoung ^{[1
]}

Kim, Ji Dang ^{[1
]}

Choi, Hyun Chul ^{[1
]}

Lee, Sunwoo ^{[1
]}

机构：

[1] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 724卷

基金：

新加坡国家研究基金会;

关键词：

Palladium; CNT; Decarboxylative coupling; Alkynyl carboxylic acid; Aryl iodides; COPPER-FREE; SELECTIVE ALKYNYLATION; CARBON; HALIDES; AIR;

D O I：

10.1016/j.jorganchem.2012.11.029

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pd-CNT nanocomposite was prepared from the composite of thiolated MWNT and Na2PdCl4. The palladium nanoparticles possess an average diameter of 2.9 nm with a narrow size distribution for the Pd-CNT. This Pd-CNT showed good activities in the coupling reactions of aryl iodides and aryl alkynyl carboxylic acids to produce the diaryl alkynes in good yields without any additional ligand. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：271 / 274

页数：4

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