Synthesis and characterization of carbon nanotube-conducting polymer thin films

被引:77
作者
Ferrer-Anglada, N
Kaempgen, M
Skákalová, V
Dettlaf-Weglikowska, U
Roth, S
机构
[1] Univ Politecn Cataluna, Dept Fis Aplicada, ES-08034 Barcelona, Spain
[2] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
关键词
carbon nanotubes; polyaniline; polypyrrole; transparent electrodes; thin films; Raman;
D O I
10.1016/j.diamond.2003.10.026
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study heterostructures were obtained as thin films of carbon nanotubes (CNTs) /conducting polymers (CP) on transparent substrates. Single-walled carbon nanotubes (SWCNTs) were deposited on a transparent substrate and used as electrodes in order to grow a thin film of CP on it electrochemically. The resulting heterostructure may be sufficiently transparent and electrically conductive to be used in practical applications. We obtained different SWCNT-CP films by using polypyrrole or polyaniline as CPs, having varied throughout the chemical and electrochemical conditions. We measured the optical absorption and electrical conductivity in order to optimize the conditions for obtaining films that have both high electrical conductivity and transparency. We analyzed the thin films that were obtained by Raman spectroscopy in order to characterize them. Raman spectroscopy shows evidence of the possible interaction between CNTs and CPs. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:256 / 260
页数:5
相关论文
共 20 条
  • [1] Ago H, 1999, ADV MATER, V11, P1281, DOI 10.1002/(SICI)1521-4095(199910)11:15<1281::AID-ADMA1281>3.0.CO
  • [2] 2-6
  • [3] Ajayan PM, 2001, TOP APPL PHYS, V80, P391
  • [4] ALIGNED CARBON NANOTUBE ARRAYS FORMED BY CUTTING A POLYMER RESIN-NANOTUBE COMPOSITE
    AJAYAN, PM
    STEPHAN, O
    COLLIEX, C
    TRAUTH, D
    [J]. SCIENCE, 1994, 265 (5176) : 1212 - 1214
  • [5] Chen GZ, 2000, ADV MATER, V12, P522, DOI 10.1002/(SICI)1521-4095(200004)12:7<522::AID-ADMA522>3.0.CO
  • [6] 2-S
  • [7] Synthesis of a new polyaniline/nanotube composite:: "in-situ" polymerisation and charge transfer through site-selective interaction
    Cochet, M
    Maser, WK
    Benito, AM
    Callejas, MA
    Martínez, MT
    Benoit, JM
    Schreiber, J
    Chauvet, O
    [J]. CHEMICAL COMMUNICATIONS, 2001, (16) : 1450 - 1451
  • [8] A complete optical study of the conductive form of polyaniline:: the emeraldine salt
    Cochet, M
    Buisson, JP
    Wéry, J
    Jonusauskas, G
    Faulques, E
    Lefrant, S
    [J]. SYNTHETIC METALS, 2001, 119 (1-3) : 389 - 390
  • [9] Carbon nanotube-polyaniline hybrid materials
    Deng, JG
    Ding, XB
    Zhang, WC
    Peng, YX
    Wang, JH
    Long, XP
    Li, P
    Chan, ASC
    [J]. EUROPEAN POLYMER JOURNAL, 2002, 38 (12) : 2497 - 2501
  • [10] DETTLAFFWEGLIKO.U, 2003, MOL NAN 17 INT WINT, P273