Synthesis and characterization of chlorodibenzyltin(IV) complexes with N,N-dialkyl dithiocarbamate ligands and crystal structure of (PhCH2)2SnCl(S2CNMe2)

被引:0
作者
Yin, HD [1 ]
Ma, CL [1 ]
Wang, Y [1 ]
机构
[1] Liaocheng Teachers Univ, Dept Chem, Liaocheng 252059, Peoples R China
来源
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2002年 / 41卷 / 02期
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thirteen chlorodibenzyltin(IV) complexes with N,N-dialkyl dithiocarbamate ligands have been synthesized by the reaction of dibenzyltin dichloride with N,N-dialkyl dithiocarbamates in 1: 1 stoichiometry and characterized by elemental analysis, UV, IR and H-1 NMR. The crystal structure of (PhCH2)(2) SnCl(S2CNMe)(2) has been determined by X-ray single crystal diffraction. The crystallographic data are as follows: triclinic, space group P-1, a=7.5750(15) Angstrom, b=10.615(2) Angstrom, c=12.059(2) Angstrom, alpha=95.053(3)degrees, beta=95.539(4)degrees, gamma=99.113(4)degrees, Z=2, V=947.6(3) Angstrom, Dx=1.600g/cm(-3), mu=1.705mm(-1), F(000)=456, R-1=0.0409, wR(2)=0.1194(Igreater than or equal to2sigma(I). The structures consist of discrete molecules containing five-coordinate tin atoms in a seriously distorted trigonal bipyramidal configuration. The molecules are packed in the unit cell as weakly-bridged dimers.
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页码:342 / 345
页数:4
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