Metal-controlled structural diversity in Co(II) and Zn(II) complexes with mixed N- and O-donors: Synthesis, characterization and property

被引：33
|
作者：
Kuai, Hai-Wei [1 ]
Cheng, Xiao-Chun [1 ]
Zhu, Xiao-Hong [1 ]
机构：
[1] Huaiyin Inst Technol, Fac Life Sci & Chem Engn, Huaian 223003, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 25卷
关键词：
Co(II) and Zn(II) complexes; Structural characterization; Fluorescence property; Antiferromagnetic interaction; LUMINESCENT PROPERTIES; COORDINATION POLYMERS; FRAMEWORKS; CONNECTIVITY; DICYANAMIDE; ZINC(II); SERIES;
D O I：
10.1016/j.inoche.2012.09.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Co(II) and Zn(II) complexes based on 1-(5-tetrazolyl)-4-(1-imidazolyl)benzene (HL) and 1,4-benzenedicarboxylic acid (H(2)pbda): [Co-2(L)(2)(pbda)(H2O)(3)] (1) and [Zn(L)(pbda)(0.5)] (2) have been prepared under hydrothermal conditions and characterized by single crystal and powder X-ray diffractions. IR, and thermogravimetric analysis. Complex 1 exhibits binodal (3.5)-connected 2D net structure with (3.5(2))(3(2).5(3).6(4).7) topology; while 2 is a binodal (3,4)-connected 2-fold interpenetrating 3D framework with dmc (4.8(2))(4.8(5)) topology. The influence of coordination geometries of metal centers on the structures of resultant complexes is discussed. Moreover, magnetic property of 1 and luminescence of 2 were investigated. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：43 / 47
页数：5
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