Metal-controlled structural diversity in Co(II) and Zn(II) complexes with mixed N- and O-donors: Synthesis, characterization and property

被引：33

作者：

Kuai, Hai-Wei ^{[1
]}

Cheng, Xiao-Chun ^{[1
]}

Zhu, Xiao-Hong ^{[1
]}

机构：

[1] Huaiyin Inst Technol, Fac Life Sci & Chem Engn, Huaian 223003, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 25卷

关键词：

Co(II) and Zn(II) complexes; Structural characterization; Fluorescence property; Antiferromagnetic interaction; LUMINESCENT PROPERTIES; COORDINATION POLYMERS; FRAMEWORKS; CONNECTIVITY; DICYANAMIDE; ZINC(II); SERIES;

D O I：

10.1016/j.inoche.2012.09.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Co(II) and Zn(II) complexes based on 1-(5-tetrazolyl)-4-(1-imidazolyl)benzene (HL) and 1,4-benzenedicarboxylic acid (H(2)pbda): [Co-2(L)(2)(pbda)(H2O)(3)] (1) and [Zn(L)(pbda)(0.5)] (2) have been prepared under hydrothermal conditions and characterized by single crystal and powder X-ray diffractions. IR, and thermogravimetric analysis. Complex 1 exhibits binodal (3.5)-connected 2D net structure with (3.5(2))(3(2).5(3).6(4).7) topology; while 2 is a binodal (3,4)-connected 2-fold interpenetrating 3D framework with dmc (4.8(2))(4.8(5)) topology. The influence of coordination geometries of metal centers on the structures of resultant complexes is discussed. Moreover, magnetic property of 1 and luminescence of 2 were investigated. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：43 / 47

页数：5

共 41 条

[1] Influence of connectivity and porosity on ligand-based luminescence in zinc metal-organic frameworks [J].

Bauer, Christina A. ;

Timofeeva, Tatiana V. ;

Settersten, Thomas B. ;

Patterson, Brian D. ;

Liu, Vincent H. ;

Simmons, Blake A. ;

Allendorf, Mark D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (22) :7136-7144

[2] Metal-Organic Framework Thin Films: From Fundamentals to Applications [J].

Betard, Angelique ;

Fischer, Roland A. .

CHEMICAL REVIEWS, 2012, 112 (02) :1055-1083

[3]

Blatov V. A., 2009, TOPOS MULTIPURPOSE C

[4] Syntheses and characterizations of three-dimensional channel-like polymeric lanthanide complexes constructed by 1,2,4,5-benzenetetracarboxylic acid [J].

Cao, R ;

Sun, DF ;

Liang, YC ;

Hong, MC ;

Tatsumi, K ;

Shi, Q .

INORGANIC CHEMISTRY, 2002, 41 (08) :2087-2094

[5]

Carlin R. L., 1986, MAGNETOCHEMISTRY

[6] Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates [J].

Chen, W ;

Wang, JY ;

Chen, C ;

Yue, Q ;

Yuan, HM ;

Chen, JS ;

Wang, SN .

INORGANIC CHEMISTRY, 2003, 42 (04) :944-946

[7] Synthesis, crystal structure and magnetic behavior of three polynuclear complexes:: [Co(pyo)2(dca)2]n, [Co3(ac)4(bpe)3(dca)2]n and [{Co(male)(H2O)2}(H2O)]n [pyo, pyridine-N-oxide; dca, dicyanamide; ac, acetate; bpe, 1,2-bis-(4-pyridyl)ethane and male, maleate] [J].

Ghoshal, D ;

Mostafa, G ;

Maji, TK ;

Zangrando, E ;

Lu, TH ;

Ribas, J ;

Chaudhuri, NR .

NEW JOURNAL OF CHEMISTRY, 2004, 28 (10) :1204-1213

[8] Elucidating the Mechanism of a Two-Step Spin Transition in a Nanoporous Metal-Organic Framework [J].

Halder, Gregory J. ;

Chapman, Karena W. ;

Neville, Suzanne M. ;

Moubaraki, Bouiemaa ;

Murray, Keith S. ;

Letard, Jean-Francois ;

Kepert, Cameron J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (51) :17552-17562

[9] Crystal structures and magnetic properties of two octacyanotungstate(IV) and (V)-cobalt(II) three-dimensional bimetallic frameworks [J].

Herrera, JM ;

Bleuzen, A ;

Dromzée, Y ;

Julve, M ;

Lloret, F ;

Verdaguer, M .

INORGANIC CHEMISTRY, 2003, 42 (22) :7052-7059

[10] Synthesis, Crystal Structures, and Photoluminescent Properties of the Cu(I)/X/α,ω-Bis(benzotriazole)alkane Hybrid Family (X = Cl, Br, I, and CN) [J].

Hu, Man-Cheng ;

Wang, Yan ;

Zhai, Quan-Guo ;

Li, Shu-Ni ;

Jiang, Yu-Cheng ;

Zhang, Yong .

INORGANIC CHEMISTRY, 2009, 48 (04) :1449-1468

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