Metal-controlled structural diversity in Co(II) and Zn(II) complexes with mixed N- and O-donors: Synthesis, characterization and property

被引：33

作者：

Kuai, Hai-Wei ^{[1
]}

Cheng, Xiao-Chun ^{[1
]}

Zhu, Xiao-Hong ^{[1
]}

机构：

[1] Huaiyin Inst Technol, Fac Life Sci & Chem Engn, Huaian 223003, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 25卷

关键词：

Co(II) and Zn(II) complexes; Structural characterization; Fluorescence property; Antiferromagnetic interaction; LUMINESCENT PROPERTIES; COORDINATION POLYMERS; FRAMEWORKS; CONNECTIVITY; DICYANAMIDE; ZINC(II); SERIES;

D O I：

10.1016/j.inoche.2012.09.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Co(II) and Zn(II) complexes based on 1-(5-tetrazolyl)-4-(1-imidazolyl)benzene (HL) and 1,4-benzenedicarboxylic acid (H(2)pbda): [Co-2(L)(2)(pbda)(H2O)(3)] (1) and [Zn(L)(pbda)(0.5)] (2) have been prepared under hydrothermal conditions and characterized by single crystal and powder X-ray diffractions. IR, and thermogravimetric analysis. Complex 1 exhibits binodal (3.5)-connected 2D net structure with (3.5(2))(3(2).5(3).6(4).7) topology; while 2 is a binodal (3,4)-connected 2-fold interpenetrating 3D framework with dmc (4.8(2))(4.8(5)) topology. The influence of coordination geometries of metal centers on the structures of resultant complexes is discussed. Moreover, magnetic property of 1 and luminescence of 2 were investigated. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：43 / 47

页数：5

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