Hierarchical MoS2@RGO nanosheets for high performance sodium storage

被引:92
作者
Che, Zongzhou [1 ,2 ]
Li, Yafeng [1 ,2 ]
Chen, Kaixiang [1 ,2 ]
Wei, Mingdeng [1 ,2 ]
机构
[1] Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
[2] Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
Sodium ion batteries; MoS2; Graphene; Nanosheets; Electrochemical property; LITHIUM-ION BATTERIES; EXCELLENT ELECTROCHEMICAL PERFORMANCE; HYDROGEN EVOLUTION REACTION; GRAPHENE OXIDE; MOS2; NANOSHEETS; MOS2/GRAPHENE COMPOSITES; ASSISTED SYNTHESIS; ANODE MATERIALS; NANOTUBES; NANOWIRES;
D O I
10.1016/j.jpowsour.2016.08.139
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The hierarchical MoS2/carbonaceous materials composites have received considerable interest for electrochemical energy storage and conversion. In the present work, the hierarchical MoS2@RGO nanosheets, where ultrathin MoS2 nanosheets perpendicularly anchor on both sides of RGO, are successfully synthesized by a new route. Such hybrid structures not only improve the conductivity of the hybrid structure and effectively prevent the aggregation of MoS2 nanosheets, but also maximize the MoS2 loading in the MoS2@RGO composites to be over 92%. The formation process for the hierarchical MoS2@RGO nanosheets is also investigated. When evaluated as an anode material for sodium-ion batteries, the hierarchical MoS2@RGO nanosheets deliver an excellent cycling performance and a high specific capacity of 420 mA h g(-1) at a current density of 100 mA g(-1). The strategy can be used to prepare other hierarchical metal sulfides@RGO nanosheets as high performance anode materials for sodium-ion batteries. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:50 / 57
页数:8
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