One-color spectroscopy of threshold electrons produced in pulsed ionization of high-lying rydberg states of naphthalene by an electric field

被引：0

作者：

Akopyan, ME ^{[1
]}

Ivanov, VS ^{[1
]}

Kleimenov, VI ^{[1
]}

Feofilov, AG ^{[1
]}

机构：

[1] St Petersburg State Univ, Inst Phys, St Petersburg 198904, Russia

来源：

OPTICS AND SPECTROSCOPY | 1999年 / 86卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

In a one-color spectrum of threshold electrons produced in pulsed ionization of long-lived (0.1-1.0 mu s) Rydberg states of naphthalene by an electric field, a new group of electrons was observed. It was attributed to the two-step excitation of high-lying Rydberg states of a molecule, which converge to the first excited electronic state of a cation. A refined value of the second adiabatic ionization energy of naphthalene was obtained (8.913 +/- 0.004 eV).

引用

页码：877 / 880

页数：4

共 44 条

[41] Photo-versus pulsed field-ionization of individual high n (n≲57) Rydberg states:: Resolved d,g series of benzene
Siglow, K
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JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (02) : 647 - 653
[42] Dynamics of high-n Rydberg states employed in zero kinetic energy-pulsed field ionization spectroscopy via the F-1 Delta(2), D-1 Pi(1), and f(3)Delta(2) Rydberg states of HCl
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Buma, WJ
deLange, CA
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JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (14) : 5702 - 5710
[43] Molecular excitation energies to high-lying bound states from time-dependent density-functional response theory: Characterization and correction of the time-dependent local density approximation ionization threshold
Casida, ME
Jamorski, C
Casida, KC
Salahub, DR
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (11) : 4439 - 4449
[44] RESONANCE-ENHANCED MULTIPHOTON IONIZATION PHOTOELECTRON-SPECTROSCOPY AND PULSED-FIELD IONIZATION VIA THE F(1)DELTA(2)(V' = 0) AND F(3)DELTA(2)(V' = 0) RYDBERG STATES OF HCI
DEBEER, E
BUMA, WJ
DELANGE, CA
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (05) : 3252 - 3261

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