Facile and Efficient Transformation of Lignocellulose into Levulinic Acid Using an AlCl3•6H2O/H3PO4 Hybrid Acid Catalyst

被引：10
|
作者：
Nemoto, Koji [1 ]
Tominaga, Ken-ichi [1 ,2 ]
Sato, Kazuhiko [1 ,2 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Interdisciplinary Res Ctr Catalyt Chem, Cent 5, Tsukuba, Ibaraki 3058565, Japan
[2] Hokkaido Univ, Catalysis Res Ctr, Kita Ku, Sapporo, Hokkaido 0010021, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2015年 / 88卷 / 12期
关键词：
BIOMASS; CONVERSION; CELLULOSE; HYDROLYSIS; OXIDATION; GLUCOSE;
D O I：
10.1246/bcsj.20150266
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Combination use of AlCl3 center dot 6H(2)O with H3PO4 has led to the development of an efficient water-tolerant catalyst system, acting cooperatively in aqueous media to produce levulinic acid from microcrystalline cellulose. This catalyst system was extended to the direct transformation of various raw biomass resources to levulinic acid in good yields.
引用
收藏
页码：1752 / 1754
页数：3
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