Halogenated Gold(III) Complexes Containing 4-Cyanopyridine: Synthesis, Characterization, and Crystal Structure

被引：8

作者：

Mohammad-Nataj, Rufia ^{[1
]}

Abedi, Anita ^{[1
]}

Amani, Vahid ^{[2
]}

机构：

[1] Islamic Azad Univ, Dept Chem, North Tehran Branch, Tehran, Iran

[2] Islamic Azad Univ, Dept Chem, Shahre Rey Branch, Tehran, Iran

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 10期

基金：

美国国家科学基金会;

关键词：

4-cyanopyridine; crystal structure; gold(III); intermolecular interaction; DNA-BINDING; PYRIDINE ADDUCTS; GOLD HALIDES; CYTOTOXICITY; REACTIVITY; AURANOFIN; KINETICS; BASICITY; AMINES;

D O I：

10.1080/15533174.2012.761236

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Au(CN-py)Cl-3] complex (1) and [Au(CN-py)Br-3] complex (2) (CN-py is 4-cyanopyridine) were prepared from the reaction of 4-cyanopyridine with HAuCl4.3H(2)O and AuBr3 in acetonitrile, respectively. Both complexes were characterized by IR, UV-Vis, H-1 NMR, and(13)C NMR spectroscopy and their structures were studied by the single-crystal X-ray diffraction method. Intermolecular C-H...Cl hydrogen bonds and Au...Cl contacts in the crystal structure of complex 1 and intermolecular C-H...Br hydrogen bonds and Au...Br and Br...N contacts in complex 2 effectively stabilize these complexes in their crystal structure.

引用

页码：1375 / 1380

页数：6

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