Halogenated Gold(III) Complexes Containing 4-Cyanopyridine: Synthesis, Characterization, and Crystal Structure

被引：8

作者：

Mohammad-Nataj, Rufia ^{[1
]}

Abedi, Anita ^{[1
]}

Amani, Vahid ^{[2
]}

机构：

[1] Islamic Azad Univ, Dept Chem, North Tehran Branch, Tehran, Iran

[2] Islamic Azad Univ, Dept Chem, Shahre Rey Branch, Tehran, Iran

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 10期

基金：

美国国家科学基金会;

关键词：

4-cyanopyridine; crystal structure; gold(III); intermolecular interaction; DNA-BINDING; PYRIDINE ADDUCTS; GOLD HALIDES; CYTOTOXICITY; REACTIVITY; AURANOFIN; KINETICS; BASICITY; AMINES;

D O I：

10.1080/15533174.2012.761236

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Au(CN-py)Cl-3] complex (1) and [Au(CN-py)Br-3] complex (2) (CN-py is 4-cyanopyridine) were prepared from the reaction of 4-cyanopyridine with HAuCl4.3H(2)O and AuBr3 in acetonitrile, respectively. Both complexes were characterized by IR, UV-Vis, H-1 NMR, and(13)C NMR spectroscopy and their structures were studied by the single-crystal X-ray diffraction method. Intermolecular C-H...Cl hydrogen bonds and Au...Cl contacts in the crystal structure of complex 1 and intermolecular C-H...Br hydrogen bonds and Au...Br and Br...N contacts in complex 2 effectively stabilize these complexes in their crystal structure.

引用

页码：1375 / 1380

页数：6

共 41 条

[1] PYRIDINE ADDUCTS OF THE GOLD HALIDES .1. SYNTHESIS AND STRUCTURE OF [HPY][AUCL4], AUCL3.PY, [AUCL2(PY)2]CL.H2O, AND [AUCL2(PY)2][AUCL2] [J].

ADAMS, HN ;

STRAHLE, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 485 (02) :65-80

[2] Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 2,2′-bipyridine, 5,5′-dimethyl-2,2′-bipyridine and chloride, [Fe(bipy)Cl4][bipy•H] and [Fe(dmbipy)2Cl2][FeCl4] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza .

POLYHEDRON, 2007, 26 (15) :4257-4262

[3]

[Anonymous], APEX2 SOFTW PACK VER

[4]

[Anonymous], SHELXTL VERS 5 1 STR

[5]

[Anonymous], MERC 1 4 1

[6] Synthesis and crystal structure of [Ni(H2O)2(pdc)(4-CNpy)] •2H2O (pdc = pyridine-2,6-dicarboxylate, 4-CNpy=4-cyanopyridine) [J].

Bhattacharyya, Manjit K. ;

Bora, Sanchay J. ;

Das, Birinchi K. .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2008, 38 (03) :195-203

[7] Synthesis and structure of products of interaction of H[AuCl4] with H2DMG and pyridine [J].

Bourosh, Paulina ;

Bologa, Olga ;

Simonov, Yurii ;

Gerbeleu, Nicolae ;

Lipkowski, Janusz ;

Gdaniec, Maria .

INORGANICA CHIMICA ACTA, 2007, 360 (10) :3250-3254

[8] Antitumor properties of some 2-[(dimethylamino)methyl]phenylgold(III) complexes [J].

Buckley, RG ;

Elsome, AM ;

Fricker, SP ;

Henderson, GR ;

Theobald, BRC ;

Parish, RV ;

Howe, BP ;

Kelland, LR .

JOURNAL OF MEDICINAL CHEMISTRY, 1996, 39 (26) :5208-5214

[9] INFLUENCE OF BASICITY AND STERIC HINDRANCE ON REACTIVITY OF AMINES TOWARD TETRACHLOROAURATE(3) ION [J].

CATTALINI, L ;

NICOLINI, M ;

ORIO, A .

INORGANIC CHEMISTRY, 1966, 5 (10) :1674-+

[10] LIGAND SUBSTITUTION KINETICS AND EQUILIBRIA IN THE SYSTEMS FORMED BY TETRABROMOAURATE(III) ANION AND HETEROCYCLIC NITROGEN DONORS [J].

CATTALINI, L ;

CHESSA, G ;

MICHELON, G ;

PITTERI, B ;

TOBE, ML ;

ZANARDO, A .

INORGANIC CHEMISTRY, 1985, 24 (21) :3409-3413

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