The limit of metastability of water under tension: theories and experiments

被引:24
作者
Herbert, E
Caupin, F
机构
[1] Univ Paris 06, Ecole Normale Super, Phys Stat Lab, F-75231 Paris 05, France
[2] Univ Paris 07, Ecole Normale Super, Phys Stat Lab, F-75231 Paris 05, France
[3] CNRS, F-75231 Paris 05, France
关键词
D O I
10.1088/0953-8984/17/45/053
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Two scenarios are proposed for explaining the thermodynamic anomalies of supercooled water, but they cannot be directly tested in this region because of the onset of homogeneous crystallization. They also give two distinct temperature dependences of the limit of metastability of water stretched beyond its boiling curve: either monotonic, as in simple liquids, or exhibiting a minimum. Therefore cavitation experiments could allow one to distinguish between the competing pictures. We review previous experiments and describe our preliminary results.
引用
收藏
页码:S3597 / S3602
页数:6
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