Synthesis and cleavage of 1,3,7-triazapyrene ethers

被引：5

作者：

Demidov, O. P. ^{[1
]}

Borovlev, I. V. ^{[1
]}

Saigakova, N. A. ^{[1
]}

Nemykina, O. A. ^{[1
]}

Pisarenko, S. V. ^{[1
]}

机构：

[1] N Caucasus Fed Univ, Stavropol 355009, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2013年 / 48卷 / 10期

关键词：

1,3,7-triazapyrenes; cleavage of ethers; tandem S-N(H)-S-N(H) alkoxylation; NUCLEOPHILIC-SUBSTITUTION; AQUEOUS-MEDIUM; ALKOXYLATION; DERIVATIVES; PYRIDAZINES; QUINOLINES; METHOXIDE; ACID;

D O I：

10.1007/s10593-013-1168-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidative alkoxylation of 1,3,7-triazapyrenes in the system ROH-H2O-KOH-K3Fe(CN)(6) leads via a tandem S (N) (H)-S (N) (H) process to the formation of 6,8-dialkoxy-1,3,7-triazapyrenes. Hydrolytic cleavage of these ethers leads to products of single or double dealkylation, depending on the reaction conditions.

引用

收藏

页码：1527 / 1532

页数：6

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