Heterocycles via cyclization of alkynes promoted by organopalladium complexes

被引：242
作者：
Cacchi, S [1 ]
机构：
[1] Univ Roma La Sapienza, Dipartimento Studi Chim & Tecnol Sostanze Biologi, I-00185 Rome, Italy
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 576卷 / 1-2期
关键词：
alkynes; catalysis; cyclization; heterocycles; palladium;
D O I：
10.1016/S0022-328X(98)01051-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two general classes of reactions leading to heterocycles are reviewed: the sequential hydroarylation(hydrovinylation)/cyclization of alkynes containing proximate nucleophilic and electrophilic centers, a process which combines the palladium-catalyzed cis addition of an aryl or vinyl unit and a hydrogen atom to the carbon-carbon triple bond with the formation of a new bond between the nucleophile and the electrophile; the palladium-catalyzed cyclization of alkynes containing proximate nucleophiles with organopalladium complexes, which is based on a trans heteropalladation/reductive elimination tandem reaction. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：42 / 64
页数：23
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