Plasmonic effect of spray-deposited Au nanoparticles on the performance of CSS CdS/CdTe solar cells

被引:14
作者
Spalatu, N. [1 ]
Hiie, J. [1 ]
Maticiuc, N. [1 ]
Krunks, M. [1 ]
Katerski, A. [1 ]
Mikli, V. [1 ]
Sildos, I. [2 ]
机构
[1] Tallinn Univ Technol, Dept Mat Sci, EE-19086 Tallinn, Estonia
[2] Univ Tartu, Inst Phys, EE-51014 Tartu, Estonia
关键词
CdS/CdTe solar cell; Au nanoparticles; Spray pyrolysis; Plasmonic effect; OPTICAL-PROPERTIES; CDTE; FILMS; ABSORPTION; BAND;
D O I
10.1016/j.apsusc.2015.04.065
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to improve the light trapping in CdTe thin-film solar cells, a coupling with plasmonic nanostructures is believed to increase the absorption as a result of the enhanced electric field and forward-scattering upon excitation of the surface plasmon resonance (SPR). The simulation studies suggest a technological feasibility of placing metallic nanoparticles on CdTe before back contacting. We have applied the chemical spray pyrolysis of different amounts of HAuCl4 ethanol solution to incorporate Au nanoparticles into CdTe and used this layer in CdS/CdTe solar cells. CdTe films show the SPR effect and an enhanced light absorption in the visible range of spectrum, whereas the CdS/CdTe solar cell have an improved conversion efficiency due to the presence of Au nanoparticles. The processes responsible for these advancements are discussed. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:69 / 73
页数:5
相关论文
共 20 条
[1]   Au/TiO2 nanosystems:: A combined RF-sputtering/sol-gel approach [J].
Armelao, L ;
Barreca, D ;
Bottaro, G ;
Gasparotto, A ;
Tondello, E ;
Ferroni, M ;
Polizzi, S .
CHEMISTRY OF MATERIALS, 2004, 16 (17) :3331-3338
[2]  
Atwater HA, 2010, NAT MATER, V9, P205, DOI [10.1038/NMAT2629, 10.1038/nmat2629]
[3]   In Situ Synthesis and Deposition of Gold Nanoparticles with Different Morphologies on Glass and ITO Substrate by Ultrasonic Spray Pyrolysis [J].
de la Garza, Maria ;
Lopez, Israel ;
Gomez, Idalia .
ADVANCES IN MATERIALS SCIENCE AND ENGINEERING, 2013, 2013
[4]   Plasmonic metallic nanostructures for efficient absorption enhancement in ultrathin CdTe-based photovoltaic cells [J].
Gu, Qilin .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (46)
[5]   Refractive index of CdTe:: Spectral and temperature dependence [J].
Hlídek, P ;
Bok, J ;
Franc, J ;
Grill, R .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (03) :1672-1674
[6]   Low-cost plasmonic solar cells prepared by chemical spray pyrolysis [J].
Kaerber, Erki ;
Katerski, Atanas ;
Acik, Ilona Oja ;
Mikli, Valdek ;
Mere, Arvo ;
Sildos, Ilmo ;
Krunks, Malle .
BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2014, 5 :2398-2402
[7]  
Kreibig U., 1995, OPTICAL PROPERTIES M, V25, P123
[8]   Deposition of gold nanoparticle films using spray pyrolysis technique: Tunability of SPR band by electric field [J].
Kumar, Neetesh ;
Komarala, Vamsi K. ;
Dutta, Viresh .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2012, 6 (9-10) :406-408
[9]   Plasmonic Au nanoparticles for enhanced broadband light absorption in inverted organic photovoltaic devices by plasma assisted physical vapour deposition [J].
Kumar, Vikas ;
Wang, Heming .
ORGANIC ELECTRONICS, 2013, 14 (02) :560-568
[10]   Close encounters between two nanoshells [J].
Lassiter, J. Britt ;
Aizpurua, Javier ;
Hernandez, Luis I. ;
Brandl, Daniel W. ;
Romero, Isabel ;
Lal, Surbhi ;
Hafner, Jason H. ;
Nordlander, Peter ;
Halas, Naomi J. .
NANO LETTERS, 2008, 8 (04) :1212-1218