Pretreatment of corn stover with diluted acetic acid for enhancement of acidogenic fermentation

被引:39
作者
Zhao, Xu [1 ]
Wang, Lijuan [2 ]
Lu, Xuebin [1 ]
Zhang, Shuting [1 ]
机构
[1] Tianjin Univ, Sch Environm Sci & Engn, Tianjin 300072, Peoples R China
[2] Aerosp Environm Engn Co Ltd, Beijing 100074, Peoples R China
基金
中国国家自然科学基金;
关键词
Pretreatment; Acetic acid; Corn stover; Acidogenic fermentation; HYDROGEN-PRODUCTION; HYDROTHERMAL PRETREATMENT; ANAEROBIC-DIGESTION; XYLOSE; OPTIMIZATION; HYDROLYSIS; STRAW;
D O I
10.1016/j.biortech.2014.01.122
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
A Box-Behnken design of response surface method was used to optimize acetic acid-catalyzed hydrothermal pretreatment of corn stover, in respect to acid concentration (0.05-0.25%), treatment time (5-15 min) and reaction temperature (180-210 degrees C). Acidogenic fermentations with different initial pH and hydrolyzates were also measured to evaluate the optimal pretreatment conditions for maximizing acid production. The results showed that pretreatment with 0.25% acetic acid at 191 degrees C for 7.74 min was found to be the most optimal condition for pretreatment of corn stover under which the production of acids can reach the highest level. Acidogenic fermentation with the hydrolyzate of pretreatment at the optimal condition at the initial pH = 5 was shown to be butyric acid type fermentation, producing 21.84 g acetic acid, 7.246 g propionic acid, 9.170 butyric acid and 1.035 g isovaleric acid from 100 g of corn stover in 900 g of water containing 2.25 g acetic acid. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:12 / 18
页数:7
相关论文
共 25 条
[1]   Effect of lignin-derived and furan compounds found in lignocellulosic hydrolysates on biomethane production [J].
Barakat, Abdellatif ;
Monlau, Florian ;
Steyer, Jean-Philippe ;
Carrere, Helene .
BIORESOURCE TECHNOLOGY, 2012, 104 :90-99
[2]  
Bi DS, 2012, FRESEN ENVIRON BULL, V21, P1283
[3]   Screening of Oleaginous Yeast Strains Tolerant to Lignocellulose Degradation Compounds [J].
Chen, Xi ;
Li, Zihui ;
Zhang, Xiaoxi ;
Hu, Fengxian ;
Ryu, Dewey D. Y. ;
Bao, Jie .
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 2009, 159 (03) :591-604
[4]  
China EPA, 2002, STANDARD METHODS EXA
[5]   Interpretation of deacetylation and hemicellulose hydrolysis during hydrothermal treatments on the basis of the severity factor [J].
Garrote, G ;
Domínguez, H ;
Parajó, JC .
PROCESS BIOCHEMISTRY, 2002, 37 (10) :1067-1073
[6]   Effect of dilute acid pretreatment of rice straw on structural properties and enzymatic hydrolysis [J].
Hsu, Teng-Chieh ;
Guo, Gia-Luen ;
Chen, Wen-Hua ;
Hwang, Wen-Song .
BIORESOURCE TECHNOLOGY, 2010, 101 (13) :4907-4913
[7]   Controlling hydrothermal reaction pathways to improve acetic acid production from carbohydrate biomass [J].
Jin, FM ;
Zhou, ZY ;
Moriya, T ;
Kishida, H ;
Higashijima, H ;
Enomoto, H .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (06) :1893-1902
[8]   Optimization of the dilute maleic acid pretreatment of wheat straw [J].
Kootstra, A. Maarten J. ;
Beeftink, Hendrik H. ;
Scott, Elinor L. ;
Sanders, Johan P. M. .
BIOTECHNOLOGY FOR BIOFUELS, 2009, 2
[9]   Comparison of dilute mineral and organic acid pretreatment for enzymatic hydrolysis of wheat straw [J].
Kootstra, A. Maarten J. ;
Beeftink, Hendrik H. ;
Scott, Elinor L. ;
Sanders, Johan P. M. .
BIOCHEMICAL ENGINEERING JOURNAL, 2009, 46 (02) :126-131
[10]   Fermentative hydrogen production from xylose using anaerobic mixed microflora [J].
Lin, Chiu-Yue ;
Cheng, Chao-Hui .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (07) :832-840