Solution phase n-doping of C60 and PCBM using tetrabutylammonium fluoride

被引：0

作者：

Weber, C. D. ^{[1
]}

Bradley, C. ^{[1
]}

Lonergan, M. C. ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 02期

关键词：

POLYMER SOLAR-CELLS; ELECTRON-TRANSFER; ABSORPTION-SPECTRA; INTERFACIAL LAYER; FULLERENES; ANIONS;

D O I：

10.1039/c3ta14132b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solution phase n-doping of C-60 and PCBM with tetrabutylammonium fluoride is shown to occur via an initial chemical reaction followed by electron transfer to a second fullerene molecule. The formation of ionic and radical intermediate species has significant implications for the use of ionically functionalized materials as electron-selective interface layers in OPVs.

引用

页码：303 / 307

页数：5

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