One-Pot Halogen-Free Synthesis of 2,3-Dihydro-1H-inden-2-yl-phosphinic Acid from 1H-indene and Elemental Phosphorus via the Trofimov-Gusarova Reaction

被引：12

作者：

Artem'ev, Alexander V. ^{[1
]}

Malysheva, Svetlana F. ^{[1
]}

Korocheva, Anastasiya O. ^{[1
]}

Bagryanskaya, Irina Yu ^{[2
]}

机构：

[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia

[2] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

HETEROATOM CHEMISTRY | 2012年 / 23卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

RED PHOSPHORUS; SUPERBASIC SYSTEMS; PHOSPHINE OXIDE; KOH-DMSO; PHOSPHORYLATION; ACTIVATION; ELECTROPHILES; METHODOLOGY; P-4;

D O I：

10.1002/hc.21051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1H-Indene reacts with red phosphorus in the superbasic KOH/DMSO(H2O) suspension at 120 degrees C for 2.5 h to give (after acidification) 2,3-dihydro-1H-inden-2-yl-phosphinic acid in 55% isolated yield. (C) 2012 Wiley Periodicals, Inc. Heteroatom Chem 23:568-573, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.21051

引用

页码：568 / 573

页数：6

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