Large Electrostrictive Strain in ( Bi0.5Na0.5) TiO3-BaTiO3-( Sr0.7Bi0.2) TiO3 Solid Solutions

被引:171
作者
Shi, Jing [1 ]
Fan, Huiqing [1 ]
Liu, Xiao [1 ]
Bell, Andrew J. [2 ]
机构
[1] Northwestern Polytech Univ, Sch Mat Sci & Engn, State Key Lab Solidificat Proc, Xian 710072, Peoples R China
[2] Univ Leeds, Sch Proc Environm & Mat, Inst Mat Res, Leeds LS2 9JT, W Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
PIEZOELECTRIC BEHAVIOR; RAMAN-SPECTROSCOPY; PHASE-TRANSITIONS; PMN-PT; TEM; NA0.5BI0.5TIO3; CERAMICS;
D O I
10.1111/jace.12712
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Relaxor ferroelectrics (0.94-x)(Bi0.5Na0.5)TiO3-0.06BaTiO(3-x)(Sr0.7Bi0.20.1)TiO3 (BNT-BT-xSBT) (0x0.5), were prepared by a solid-state reaction process, and their structures were characterized by the transmission electron microscopy and Raman spectroscopy. The BNT-BT-0.3SBT has a very high electrostrictive strain S=0.152% with hysteresis-free behavior, much more than the reported S in other ferroelectrics. S-P-2 profiles perfectly follow the quadratic relation, which indicates a purely electrostrictive effect with a high electrostrictive coefficient (Q(11)) of 0.0297m(4)/C-2. Even, its Q(11) keeps at a high level in the temperature range from ambient temperature to 180 degrees C. The field-induced large electrostrictive strain of BNT-BT-0.3SBT was attributed to the existence of ferroelectric nanodomains.
引用
收藏
页码:848 / 853
页数:6
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