Solventless acetylation of alcohols and phenols catalyzed by supported iron oxide nanoparticles

被引:25
作者
Rajabi, Fatemeh [1 ]
Luque, Rafael [2 ,3 ]
机构
[1] Payame Noor Univ, Dept Sci, Tehran, Iran
[2] Univ Cordoba, Dept Quim Organ, E-14014 Cordoba, Spain
[3] Hong Kong Univ Sci & Technol, Dept Chem & Biomol Engn, Kowloon, Hong Kong, Peoples R China
关键词
Supported iron oxide nanoparticles; Acetylation; Solventless reactions; Heterogeneous catalyst; HIGHLY EFFICIENT CATALYST; ACYLATION CATALYST; POWERFUL CATALYST; ACETIC-ANHYDRIDE; AMINES; THIOLS; MILD; ACID; OXIDATION; ALDEHYDES;
D O I
10.1016/j.catcom.2013.11.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Supported iron oxide nanoparticles on silicate catalysts were found to be efficient and easily recoverable materials in the acetylation of alcohols and phenols to their corresponding acetyl compounds using acetic anhydride under mild and solvent-less conditions. The supported iron oxide nanoparticles could be easily recovered from the reaction mixture and reused ten times without any loss in activity. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:129 / 132
页数:4
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