A modular approach to ligands for asymmetric pi-allyl palladium catalysed additions

被引：39
作者：
Gilbertson, SR
Chang, CWT
机构：
[1] Department of Chemistry, Washington University, St. Louis
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 10期
关键词：
D O I：
10.1039/a607200c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A route to phosphinodihydrooxazoles is reported, which is used to synthesize ten new ligands whose ability to asymmetrically catalyse the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate is investigated; the best gave a palladium complex which catalyses the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate in 99% yield and 97% ee.
引用
收藏
页码：975 / 976
页数：2
相关论文
共 15 条
12