Photoelectrochemical effect in dye sensitized, sputter deposited Ti oxide films:: The role of thickness-dependent roughness and porosity

被引：23

作者：

Gómez, M

Rodríguez, J

Tingry, S

Hagfeldt, A

Lindquist, SE

Granqvist, CG

机构：

[1] Univ Uppsala, Angstrom Lab, Dept Mat Sci, SE-75121 Uppsala, Sweden

[2] Univ Grenoble 1, Lab Electrochim Organ & Photochim Redox, CNRS, UMR 5630, F-38401 Grenoble 9, France

[3] Univ Uppsala, Dept Phys Chem, SE-75121 Uppsala, Sweden

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 1999年 / 59卷 / 03期

关键词：

thin films; Ti oxide; solar cells; photoelectric effects; sputtering; electrochemistry;

D O I：

10.1016/S0927-0248(99)00044-6

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Ti oxide films were made by reactive DC magnetron sputtering onto electrically conducting glass substrates. The films were dye sensitized with an Ru complex, thereby yielding nanocrystalline solar cells. We investigated the microstructure of the films by X-ray diffraction, scanning electron microscopy, atomic force microscopy, and cyclic voltammetry on viologen-containing samples. The internal surface area was enhanced with increasing film thickness, and this property could be correlated with an enlarged photoelectric conversion efficiency. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：277 / 287

页数：11

共 17 条

[1] BARD AJ, 1980, ELECTROCHEMICAL METH, P521
[2] Cullity B.D., 1959, ELEMENTS XRAY DIFFRA
[3] *DIG INSTR INC, 1993, NAN 3 COMM REF MAN V
[4] SYNTHESIS AND CHARACTERIZATION OF A BENZYLVIOLOGEN SURFACE-DERIVATIZING REAGENT - N,N'-BIS[P-(TRIMETHOXYSILYL)BENZYL]-4,4'-BIPYRIDINIUM DICHLORIDE
DOMINEY, RN
LEWIS, TJ
WRIGHTON, MS
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (26) : 5345 - 5354
[5] Photoelectrochemical studies of dye-sensitized polycrystalline titanium oxide thin films prepared by sputtering
Gómez, M
Rodríguez, J
Lindquist, SE
Granqvist, CG
[J]. THIN SOLID FILMS, 1999, 342 (1-2) : 148 - 152
[6] NANOCRYSTALLINE SOLAR-CELLS
GRATZEL, M
[J]. RENEWABLE ENERGY, 1994, 5 (1-4) : 118 - 133
[7] PHOTOELECTROCHEMICAL STUDIES OF COLLOIDAL TIO2-FILMS - THE CHARGE SEPARATION PROCESS STUDIED BY MEANS OF ACTION SPECTRA IN THE UV REGION
HAGFELDT, A
BJORKSTEN, U
LINDQUIST, SE
[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1992, 27 (04) : 293 - 304
[8] Charge recombination in dye-sensitized nanocrystalline TiO2 solar cells
Huang, SY
Schlichthorl, G
Nozik, AJ
Gratzel, M
Frank, AJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14): : 2576 - 2582
[9] Preparation of TiO2-based powders with high photocatalytic activities
Kasuga, T
Hiramatsu, M
Hirano, M
Hoson, A
Oyamada, K
[J]. JOURNAL OF MATERIALS RESEARCH, 1997, 12 (03) : 607 - 609
[10] ANGULAR-SELECTIVE OPTICAL TRANSMITTANCE OF ANISOTROPIC INHOMOGENEOUS CR-BASED FILMS MADE BY SPUTTERING
LEBELLAC, D
NIKLASSON, GA
GRANQVIST, CG
[J]. JOURNAL OF APPLIED PHYSICS, 1995, 77 (12) : 6145 - 6151

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