Vacuum tribological performance of phosphonium-based ionic liquids as lubricants and lubricant additives of multialkylated cyclopentanes

被引:59
作者
Zhang, Songwei [1 ,2 ]
Hu, Litian [1 ]
Qiao, Dan [1 ,2 ]
Feng, Dapeng [1 ]
Wang, Haizhong [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
Vacuum; Phosphonium-based ionic liquids; Seizure-like high friction; Additive solubility; POLY(ETHYLENE GLYCOL); ANTIWEAR; CONTACTS; FLUIDS; SPACE; OIL;
D O I
10.1016/j.triboint.2013.06.012
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
The tribological effects of tetraalkylphosphonium phosphate ionic liquids (PP-ILs) as lubricants and lubricant additives of multialkylated cyclopentanes (MACs) was evaluated in vacuum (10(-4) Pa) by a vacuum four-ball tribometer. Results showed that the transient seizure-like high friction appearing for MACs could be effectively eliminated by neat PP-ILs or by adding the PP-ILs with long alkyl chain into MACs. Confirmed by the surface analysis, the improved tribological performances could be ascribed to the high load-carrying capacity of ionic liquids and the protective films formed on the contact surfaces through the tribochemical reaction between the PP-ILs and fresh steel surfaces under the boundary lubrication. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:289 / 295
页数:7
相关论文
共 31 条
[1]   Ionic Liquids: Past, present and future [J].
Angell, C. Austen ;
Ansari, Younes ;
Zhao, Zuofeng .
FARADAY DISCUSSIONS, 2012, 154 :9-27
[2]  
[Anonymous], 2000, J SYNTH LUBR, DOI DOI 10.1002/JSL.3000170203
[3]   Ionic Liquids as Advanced Lubricant Fluids [J].
Bermudez, Maria-Dolores ;
Jimenez, Ana-Eva ;
Sanes, Jose ;
Carrion, Francisco-Jose .
MOLECULES, 2009, 14 (08) :2888-2908
[4]   Industrial preparation of phosphonium ionic liquids [J].
Bradaric, CJ ;
Downard, A ;
Kennedy, C ;
Robertson, AJ ;
Zhou, YH .
GREEN CHEMISTRY, 2003, 5 (02) :143-152
[5]  
Burke J., 1984, Solubility Parameters: Theory and Application, V3
[6]   Imidazolium Ionic Liquids As Antiwear and Antioxidant Additive in Poly(ethylene glycol) for Steel/Steel Contacts [J].
Cai, Meirong ;
Liang, Yongmin ;
Yao, Meihuan ;
Xia, Yanqiu ;
Zhou, Feng ;
Liu, Weimin .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (03) :870-876
[7]   1-N-alkyl-3-methylimidazolium ionic liquids as neat lubricants and lubricant additives in steel-aluminium contacts [J].
Jiménez, AE ;
Bermúdez, MD ;
Iglesias, P ;
Carrión, FJ ;
Martínez-Nicolás, G .
WEAR, 2006, 260 (7-8) :766-782
[8]   Imidazolium ionic liquids as additives of the synthetic ester propylene glycol dioleate in aluminium-steel lubrication [J].
Jimenez, Ana-Eva ;
Bermudez, Maria-Dolores .
WEAR, 2008, 265 (5-6) :787-798
[9]  
Jones Jr WR, NASACR2005213424
[10]   Evaluation of several space lubricants using a vacuum four-ball tribometer [J].
Jones, WR ;
Poslowski, AK ;
Shogrin, BA ;
Herrera-Fierro, P ;
Jansen, MJ .
TRIBOLOGY TRANSACTIONS, 1999, 42 (02) :317-323